Electroanalytical determination of the sunscreen agent octocrylene in cosmetic products
Identifieur interne : 000317 ( Main/Exploration ); précédent : 000316; suivant : 000318Electroanalytical determination of the sunscreen agent octocrylene in cosmetic products
Auteurs : J. B. G. Junior [Brésil] ; T. A. Araujo [Brésil] ; M. A. G. Trindade [Brésil] ; V. S. Ferreira [Brésil]Source :
- International journal of cosmetic science [ 0142-5463 ] ; 2012.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Analyse quantitative, Carbone.
English descriptors
- KwdEn :
Abstract
An electroanalytical method was developed to detect and quantify the sunscreen agent octocrylene (OCR) in cosmetic products. The method was based on electrochemical reduction, using voltammetric techniques. OCR was reduced at -0.97 V vs. Ag/AgCl on a glassy carbon electrode using a mixture of Britton-Robinson buffer (0.04 mol L-1) and ethanol (7: 3, v/v) as the supporting electrolyte solution. Under optimized conditions and square-wave voltammetry. OCR response was linear from 5.0 x 10-6 to 8.0 x 10-5 mol L-1 (r = 0.9995), with a limit of detection of 2.8 x 10-6 mol L-1. The proposed electroanalytical method proved simple, fast and suitable for detection and quantification of OCR in samples of cosmetic products, with satisfactory results in the recovery test and analytical determination in real samples.
Affiliations:
Links toward previous steps (curation, corpus...)
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Le document en format XML
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<series><title level="j" type="main">International journal of cosmetic science</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Carbon</term>
<term>Chemical analysis</term>
<term>Chemical reduction</term>
<term>Cosmetic</term>
<term>Electrochemical detector</term>
<term>Electrochemical reaction</term>
<term>Electrodes</term>
<term>Glassy state</term>
<term>Octocrilene</term>
<term>Quantitative analysis</term>
<term>Square wave</term>
<term>Sunscreen product</term>
<term>Voltammetry</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Analyse quantitative</term>
<term>Produit antisolaire</term>
<term>Octocrilène</term>
<term>Cosmétique</term>
<term>Electrode</term>
<term>Analyse chimique</term>
<term>Carbone</term>
<term>Etat vitreux</term>
<term>Réduction chimique</term>
<term>Onde carrée</term>
<term>Voltammétrie</term>
<term>Détecteur électrochimique</term>
<term>Réaction électrochimique</term>
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<front><div type="abstract" xml:lang="en">An electroanalytical method was developed to detect and quantify the sunscreen agent octocrylene (OCR) in cosmetic products. The method was based on electrochemical reduction, using voltammetric techniques. OCR was reduced at -0.97 V vs. Ag/AgCl on a glassy carbon electrode using a mixture of Britton-Robinson buffer (0.04 mol L<sup>-1</sup>
) and ethanol (7: 3, v/v) as the supporting electrolyte solution. Under optimized conditions and square-wave voltammetry. OCR response was linear from 5.0 x 10<sup>-6</sup>
to 8.0 x 10-<sup>5</sup>
mol L<sup>-1</sup>
(r = 0.9995), with a limit of detection of 2.8 x 10<sup>-6</sup>
mol L<sup>-1</sup>
. The proposed electroanalytical method proved simple, fast and suitable for detection and quantification of OCR in samples of cosmetic products, with satisfactory results in the recovery test and analytical determination in real samples.</div>
</front>
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<affiliations><list><country><li>Brésil</li>
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<tree><country name="Brésil"><noRegion><name sortKey="Junior, J B G" sort="Junior, J B G" uniqKey="Junior J" first="J. B. G." last="Junior">J. B. G. Junior</name>
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<name sortKey="Ferreira, V S" sort="Ferreira, V S" uniqKey="Ferreira V" first="V. S." last="Ferreira">V. S. Ferreira</name>
<name sortKey="Trindade, M A G" sort="Trindade, M A G" uniqKey="Trindade M" first="M. A. G." last="Trindade">M. A. G. Trindade</name>
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